000 -LEADER |
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02618nam a22004455i 4500 |
003 - CONTROL NUMBER IDENTIFIER |
control field |
OSt |
005 - DATE AND TIME OF LATEST TRANSACTION |
control field |
20140310153332.0 |
007 - PHYSICAL DESCRIPTION FIXED FIELD--GENERAL INFORMATION |
fixed length control field |
cr nn 008mamaa |
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
fixed length control field |
120103s2012 gw | s |||| 0|eng d |
020 ## - INTERNATIONAL STANDARD BOOK NUMBER |
International Standard Book Number |
9783642243615 |
|
978-3-642-24361-5 |
050 #4 - LIBRARY OF CONGRESS CALL NUMBER |
Classification number |
QD415-436 |
082 04 - DEWEY DECIMAL CLASSIFICATION NUMBER |
Classification number |
547 |
Edition number |
23 |
264 #1 - |
-- |
Berlin, Heidelberg : |
-- |
Springer Berlin Heidelberg, |
-- |
2012. |
912 ## - |
-- |
ZDB-2-CMS |
100 1# - MAIN ENTRY--PERSONAL NAME |
Personal name |
Qiu, Zaozao. |
Relator term |
author. |
245 10 - IMMEDIATE SOURCE OF ACQUISITION NOTE |
Title |
Late Transition Metal-Carboryne Complexes |
Medium |
[electronic resource] : |
Remainder of title |
Synthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes / |
Statement of responsibility, etc |
by Zaozao Qiu. |
300 ## - PHYSICAL DESCRIPTION |
Extent |
XVIII, 134 p. |
Other physical details |
online resource. |
440 1# - SERIES STATEMENT/ADDED ENTRY--TITLE |
Title |
Springer Theses |
505 0# - FORMATTED CONTENTS NOTE |
Formatted contents note |
Introduction -- Nickel-1,2-o-Carboryne Complexes -- Nickel-Mediated Coupling Reactions of 1,2-o-Carboryne with Alkenes -- Nickel-Mediated/Catalyzed Three-Component Cycloaddition Reaction of 1,2-o-Carboryne/Arynes, Alkenes, and Alkynes -- Nickel-Catalyzed Regioselective [2+2+2] Cycloaddition of 1,2-o-Carboryne with Alkynes -- Palladium/Nickel-Cocatalyzed [2+2+2] Cycloaddition of 1,3-o-Carboryne with Alkynes -- Conclusion -- Experimental Section. |
520 ## - SUMMARY, ETC. |
Summary, etc |
In this thesis, Zaozao Qiu shows that transition metals can mediate or catalyze cycloaddition and coupling reactions of carboryne with alkynes or alkenes. These reactions afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes, and are powerful strategies to assemble useful complex molecules in a single operation from very simple precursors. Carboranes have many applications in medicine. However, their unique structures make derivatization difficult and until now limited efficient synthetic methods to obtain functional carborane materials have restricted their application. This work breaks new ground in metal-carboryne chemistry and will have a significant impact on synthetic, cluster and materials chemistry. |
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
Topical term or geographic name as entry element |
Chemistry. |
|
Topical term or geographic name as entry element |
Chemistry, inorganic. |
|
Topical term or geographic name as entry element |
Chemistry, Organic. |
|
Topical term or geographic name as entry element |
Biochemistry. |
|
Topical term or geographic name as entry element |
Chemistry. |
|
Topical term or geographic name as entry element |
Organic Chemistry. |
|
Topical term or geographic name as entry element |
Inorganic Chemistry. |
|
Topical term or geographic name as entry element |
Medicinal Chemistry. |
710 2# - ADDED ENTRY--CORPORATE NAME |
Corporate name or jurisdiction name as entry element |
SpringerLink (Online service) |
773 0# - HOST ITEM ENTRY |
Title |
Springer eBooks |
776 08 - ADDITIONAL PHYSICAL FORM ENTRY |
Display text |
Printed edition: |
International Standard Book Number |
9783642243608 |
856 40 - ELECTRONIC LOCATION AND ACCESS |
Uniform Resource Identifier |
http://dx.doi.org/10.1007/978-3-642-24361-5 |
942 ## - ADDED ENTRY ELEMENTS (KOHA) |
Source of classification or shelving scheme |
|
Item type |
E-Book |