000 -LEADER |
fixed length control field |
02809nam a22004335i 4500 |
003 - CONTROL NUMBER IDENTIFIER |
control field |
OSt |
005 - DATE AND TIME OF LATEST TRANSACTION |
control field |
20140310153332.0 |
007 - PHYSICAL DESCRIPTION FIXED FIELD--GENERAL INFORMATION |
fixed length control field |
cr nn 008mamaa |
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
fixed length control field |
120516s2012 gw | s |||| 0|eng d |
020 ## - INTERNATIONAL STANDARD BOOK NUMBER |
International Standard Book Number |
9783642293818 |
|
978-3-642-29381-8 |
050 #4 - LIBRARY OF CONGRESS CALL NUMBER |
Classification number |
QD95-96 |
082 04 - DEWEY DECIMAL CLASSIFICATION NUMBER |
Classification number |
543.2-543.8 |
Edition number |
23 |
264 #1 - |
-- |
Berlin, Heidelberg : |
-- |
Springer Berlin Heidelberg : |
-- |
Imprint: Springer, |
-- |
2012. |
912 ## - |
-- |
ZDB-2-CMS |
100 1# - MAIN ENTRY--PERSONAL NAME |
Personal name |
Brogaard, Rasmus Y. |
Relator term |
author. |
245 10 - IMMEDIATE SOURCE OF ACQUISITION NOTE |
Title |
Molecular Conformation and Organic Photochemistry |
Medium |
[electronic resource] : |
Remainder of title |
Time-resolved Photoionization Studies / |
Statement of responsibility, etc |
by Rasmus Y. Brogaard. |
300 ## - PHYSICAL DESCRIPTION |
Extent |
XVI, 122 p. 50 illus., 19 illus. in color. |
Other physical details |
online resource. |
440 1# - SERIES STATEMENT/ADDED ENTRY--TITLE |
Title |
Springer Theses, Recognizing Outstanding Ph.D. Research, |
International Standard Serial Number |
2190-5053 |
505 0# - FORMATTED CONTENTS NOTE |
Formatted contents note |
Aspects and investigation of photochemical dynamics -- A time-resolved probing method: photoionization -- Simulation of time-resolved photoionization signals -- Simulation: the Norrish type-I reaction in acetone -- Experimental setups -- Paracyclophanes I: [2+2]cycloaddition of ethylenes -- Paracyclophanes II: The Paternò-Büchi reaction -- Probing structural dynamics by interaction between chromophores. |
520 ## - SUMMARY, ETC. |
Summary, etc |
Rasmus Brogaard's thesis digs into the fundamental issue of how the shape of a molecules relates to its photochemical reactivity. This relation is drastically different from that of ground-state chemistry, since lifetimes of excited states are often comparable to or even shorter than the time scales of conformational changes. Combining theoretical and experimental efforts in femto-second time-resolved photoionization Rasmus Brogaard finds that a requirement for an efficient photochemical reaction is the prearrangement of the constituents in a reactive conformation. Furthermore, he is able to show that by exploiting a strong ionic interaction between two chromophores, a coherent molecular motion can be induced and probed in real-time. This way of using bichromophoric interactions provides a promising strategy for future research on conformational dynamics. |
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
Topical term or geographic name as entry element |
Chemistry. |
|
Topical term or geographic name as entry element |
Spectroscopy. |
|
Topical term or geographic name as entry element |
Chemistry, Physical organic. |
|
Topical term or geographic name as entry element |
Chemistry. |
|
Topical term or geographic name as entry element |
Spectroscopy/Spectrometry. |
|
Topical term or geographic name as entry element |
Atomic/Molecular Structure and Spectra. |
|
Topical term or geographic name as entry element |
Physical Chemistry. |
710 2# - ADDED ENTRY--CORPORATE NAME |
Corporate name or jurisdiction name as entry element |
SpringerLink (Online service) |
773 0# - HOST ITEM ENTRY |
Title |
Springer eBooks |
776 08 - ADDITIONAL PHYSICAL FORM ENTRY |
Display text |
Printed edition: |
International Standard Book Number |
9783642293801 |
856 40 - ELECTRONIC LOCATION AND ACCESS |
Uniform Resource Identifier |
http://dx.doi.org/10.1007/978-3-642-29381-8 |
942 ## - ADDED ENTRY ELEMENTS (KOHA) |
Source of classification or shelving scheme |
|
Item type |
E-Book |