000 -LEADER |
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02458nam a22004455i 4500 |
003 - CONTROL NUMBER IDENTIFIER |
control field |
OSt |
005 - DATE AND TIME OF LATEST TRANSACTION |
control field |
20140310153333.0 |
007 - PHYSICAL DESCRIPTION FIXED FIELD--GENERAL INFORMATION |
fixed length control field |
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008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
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120829s2013 gw | s |||| 0|eng d |
020 ## - INTERNATIONAL STANDARD BOOK NUMBER |
International Standard Book Number |
9783642320514 |
|
978-3-642-32051-4 |
050 #4 - LIBRARY OF CONGRESS CALL NUMBER |
Classification number |
QD415-436 |
082 04 - DEWEY DECIMAL CLASSIFICATION NUMBER |
Classification number |
547 |
Edition number |
23 |
264 #1 - |
-- |
Berlin, Heidelberg : |
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Springer Berlin Heidelberg : |
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Imprint: Springer, |
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2013. |
912 ## - |
-- |
ZDB-2-CMS |
100 1# - MAIN ENTRY--PERSONAL NAME |
Personal name |
Hutchby, Marc. |
Relator term |
author. |
245 10 - IMMEDIATE SOURCE OF ACQUISITION NOTE |
Title |
Novel Synthetic Chemistry of Ureas and Amides |
Medium |
[electronic resource] / |
Statement of responsibility, etc |
by Marc Hutchby. |
300 ## - PHYSICAL DESCRIPTION |
Extent |
XVII, 166 p. 358 illus., 41 illus. in color. |
Other physical details |
online resource. |
440 1# - SERIES STATEMENT/ADDED ENTRY--TITLE |
Title |
Springer Theses, Recognizing Outstanding Ph.D. Research, |
International Standard Serial Number |
2190-5053 |
505 0# - FORMATTED CONTENTS NOTE |
Formatted contents note |
Transition metal catalysis -- Palladium catalysis -- Pd(II) catalysed aminocarbonylation of alkenes -- Carbonylation of aryl ureas -- Urea Hydrolysis -- Amide hydrolysis. |
520 ## - SUMMARY, ETC. |
Summary, etc |
In this thesis, the author investigates the chemistry and application of molecules containing urea and amide bonds. These bonds are some of the strongest known and are fundamental to biological processes. The author describes his discovery that sterically hindered ureas undergo solvolysis at room temperature under neutral conditions. This is a remarkable finding, since ureas are inert under these conditions and a general rule of chemistry is that hindered substrates are less reactive. Remarkably, the author translates these results to the correspondingly sterically hindered amides. This thesis has resulted in a number of outstanding publications in high profile journals. The unique method for breaking urea and amide bonds developed in this study is likely to have far reaching consequences for biological protein manipulation. |
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
Topical term or geographic name as entry element |
Chemistry. |
|
Topical term or geographic name as entry element |
Chemistry, Organic. |
|
Topical term or geographic name as entry element |
Catalysis. |
|
Topical term or geographic name as entry element |
Biochemistry. |
|
Topical term or geographic name as entry element |
Chemistry. |
|
Topical term or geographic name as entry element |
Organic Chemistry. |
|
Topical term or geographic name as entry element |
Catalysis. |
|
Topical term or geographic name as entry element |
Protein Science. |
710 2# - ADDED ENTRY--CORPORATE NAME |
Corporate name or jurisdiction name as entry element |
SpringerLink (Online service) |
773 0# - HOST ITEM ENTRY |
Title |
Springer eBooks |
776 08 - ADDITIONAL PHYSICAL FORM ENTRY |
Display text |
Printed edition: |
International Standard Book Number |
9783642320507 |
856 40 - ELECTRONIC LOCATION AND ACCESS |
Uniform Resource Identifier |
http://dx.doi.org/10.1007/978-3-642-32051-4 |
942 ## - ADDED ENTRY ELEMENTS (KOHA) |
Source of classification or shelving scheme |
|
Item type |
E-Book |